L. Mutihac et Do. Popescu, CROWN-ETHERS IN SOLVENT-EXTRACTION PROCESSES .2. EXTRACTION CONSTANTSOF AMINO-ACIDS WITH SOME CROWN-ETHERS, Revue Roumaine de Chimie, 38(12), 1993, pp. 1491-1497
The posibility of macrocyclic ligands: 18-crown-6, dibenzo-18-crown-6
and dicyclo-hexyl-18-crown-6, to complex the amino acids (L-leucine, D
L-tryptophane, L-isoleucine, L-phenylalanine, L-valine and glycine) in
protonated form were studied. The extraction constants were determine
d by a spectrophotometric visible absorption method. Diphenylamino-azo
benzene-p-sulphonic acid anion was use as counterion.