SOLUBILIZATION OF LANTHANIDE IONS BY CYCLODEXTRINS IN BASIC AQUEOUS-SOLUTIONS

Authors
YASHIRO M MIYAMA S TAKARADA T KOMIYAMA M
Citation
M. Yashiro et al., SOLUBILIZATION OF LANTHANIDE IONS BY CYCLODEXTRINS IN BASIC AQUEOUS-SOLUTIONS, Journal of inclusion phenomena and molecular recognition in chemistry, 17(4), 1994, pp. 393-397
Citations number
24
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
17
Issue
4
Year of publication
1994
Pages
393 - 397
Database
ISI
SICI code
0923-0750(1994)17:4<393:SOLIBC>2.0.ZU;2-K
Abstract
Cyclodextrins form complexes with lanthanide ions in basic aqueous sol utions. This complex formation in basic solution dramatically enhances the solubility of lanthanide ions, which are otherwise insoluble due to the formation of hydroxide gels. Solutions of the gamma-cyclodextri n-Ce3+ complex effectively hydrolyze 2'-deoxyadenosine-5'-monophosphat e to 2'-deoxyadenosine.