The precautions which have to be taken in measuring electro-optical co
efficients of some semiconductors are emphasized. It is shown that cla
ssical measurements using a lock-in amplifier may lead to erroneous re
sults if ohmic contacts are not obtained. In presence of Schottky cont
acts, electro-optical coefficients may still be determined provided th
at measurements are performed in dc fields and that also an adequate t
heoretical model based on a linear distribution of the electric field
at the interfaces is used. The model is tested with the electro-optica
l semiconductor CdIn2Te4. Electrical properties of contacts were inves
tigated by using I-V and C-V measurements. Then electro-optical measur
ements in ac and dc fields are compared. Special attention is paid to
dc measurements, and results are in very good agreement with those pre
dicted by the model. Finally, a value of the electro-optical coefficie
nt r41 of CdIn2Te4 close to 3 pm V-1, and not 50 pm V-1 as already ann
ounced, is found.