B. Pivac et al., SPECTROSCOPIC STUDY OF SIC-LIKE STRUCTURES FORMED ON POLYCRYSTALLINE SILICON SHEETS DURING GROWTH, Journal of applied physics, 75(7), 1994, pp. 3586-3592
Edge-defined film-fed grown polycrystalline silicon sheets, grown with
one face exposed to oxidizing CO gas added to the inert Ar atmosphere
, were studied. Interaction of CO with molten silicon surface during g
rowth produced SiC-like structures in a thin layer on the surface expo
sed to CO. Infrared spectroscopy results suggest that this layer is co
nstituted of good quality SiC; however, Raman and x-ray photoelectron
spectroscopy showed that it consists of Si1-xCx in the form of small c
rystallites mixed with C- and O-rich silicon.