A method is described for complete separation of bismuth(III) from aqu
eous solutions as colloidal sulphide precipitate using sodium sulphide
as a precipitant and oleic acid as a surfactant. Hydrogen ion concent
ration appears to be an important factor affecting the floatation proc
ess. At pH 1.0 bismuth(III) was completely floated. The floatation of
bismuth(III) was successful in the presence of some foreign ions. It w
as found that, the order of the additive additive reagents and the tem
perature markedly affect the floatability. Moreover, ionic strength ha
s no appreciable effect on the floatation efficiency. A suggested mech
anism for the floatation process has been proposed.