The technique of electron-stimulated desorption ion angular distributi
on (ESDIAD) has emerged in its own right over the last decade as a mea
ns of determining the geometry of surface, adsorbed species. The princ
iples underlying the operation and limits of the technique will be bri
efly discussed, and, in turn, (1) findings at interfaces of silicon wi
th adsorbed water, and (2) recent work at oxide TiO2 surfaces, both cl
ean and with adsorbed gases, are outlined.