PALLADIUM-CATALYZED COUPLING OF VINYLFERROCENE WITH AROMATIC HALIDES - A HIGHLY EFFICIENT ROUTE TO (FERROCENYLVINYL)ARENES

Authors
KONIG B ZIEG H BUBENITSCHEK P JONES PG
Citation
B. Konig et al., PALLADIUM-CATALYZED COUPLING OF VINYLFERROCENE WITH AROMATIC HALIDES - A HIGHLY EFFICIENT ROUTE TO (FERROCENYLVINYL)ARENES, Chemische Berichte, 127(9), 1994, pp. 1811-1813
Citations number
33
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
127
Issue
9
Year of publication
1994
Pages
1811 - 1813
Database
ISI
SICI code
0009-2940(1994)127:9<1811:PCOVWA>2.0.ZU;2-K
Abstract
(Ferrocenylvinyl)arenes 3, 5, and 7 are obtained from vinylferrocene ( 1) and substituted aromatic and heteroaromatic halides by palladium-ca talyzed Heck-type reactions. Up to three ferrocene units are introduce d in one step by the multifold reaction of 1,2-dibromo- (4) or 1,3,5-t ribromobenzene (6) with 1. The first crystal structure of a bis(ferroc enylvinyl)benzene chromophore (5) is reported.