The response of a novel fiber-optic Raman probe to low levels of trich
loroethylene (TCE) vapors is characterized. The detection limit of the
current probe for TCE vapor is 34 mg/L, and the probe exhibits a full
y reversible response. The probe uses an organic-polymer, low-density
polyethylene to concentrate TCE vapors in the optical path of the fibe
r-optic Raman spectrometer. The relative standard deviation for measur
ement of 677 mg/L of TCE in the vapor is 0.3%.