TERTIARY PHOSPHINES AND P-CHIRAL PHOSPHINITES BEARING A FULLERENE SUBSTITUENT

Citation
S. Yamago et al., TERTIARY PHOSPHINES AND P-CHIRAL PHOSPHINITES BEARING A FULLERENE SUBSTITUENT, Journal of the Chemical Society, Chemical Communications, (18), 1994, pp. 2093-2094
Citations number
15
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
18
Year of publication
1994
Pages
2093 - 2094
Database
ISI
SICI code
0022-4936(1994):18<2093:TPAPPB>2.0.ZU;2-W
Abstract
The reaction of a lithiated phosphine-borane or a posphinite borane wi th C-60 followed by removal of the BH3 group affords a phosphine or a phosphinite bearing a fullerene substituent, wh ich undergoes complexa tion with BH3 a nd PtCl2 selectively on the phosphorus atom with 1:1 a nd 2:1 stoichiometry.