DIMERIC PORPHYRINS LINKED BY CONJUGATED GROUPS CONTAINING TRIPLE BONDS - THE CRYSTAL-STRUCTURE OF THE NICKEL OCTAETHYLPORPHYRIN DIMER BRIDGED BY 2,5-DIETHYNYLTHIOPHENE

Authors
ARNOLD DP JAMES DA KENNARD CHL SMITH G
Citation
Dp. Arnold et al., DIMERIC PORPHYRINS LINKED BY CONJUGATED GROUPS CONTAINING TRIPLE BONDS - THE CRYSTAL-STRUCTURE OF THE NICKEL OCTAETHYLPORPHYRIN DIMER BRIDGED BY 2,5-DIETHYNYLTHIOPHENE, Journal of the Chemical Society, Chemical Communications, (18), 1994, pp. 2131-2132
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1994
Pages
2131 - 2132
Database
ISI
SICI code
0022-4936(1994):18<2131:DPLBCG>2.0.ZU;2-M
Abstract
The conjugated bridge and the attached mese-carbons in the title dimer are almost coplanar; the porphyrin rings are ruffled and distorted in this vicinity, indicating strong interporphyrin interaction via the p i-orbitals of the diethynylthiophene unit.