TRINUCLEAR SPECIES IN VANADIUM(II) CHEMISTRY

Authors
HUGHES DL LARKWORTHY LF LEIGH GJ MCGARRY CJ SANDERS JR SMITH GW DESOUZA JS
Citation
Dl. Hughes et al., TRINUCLEAR SPECIES IN VANADIUM(II) CHEMISTRY, Journal of the Chemical Society, Chemical Communications, (18), 1994, pp. 2137-2138
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1994
Pages
2137 - 2138
Database
ISI
SICI code
0022-4936(1994):18<2137:TSIVC>2.0.ZU;2-H
Abstract
The triangulo-(V3Cl3) unit is shown to form easily in solutions from m ononuclear vanadium(II) compounds:such as [VCl2(tmeda)(2)] and structu ral studies show that this unit is contained in a trigonal bipyramidal arrangement with either chloride ions or methoxide ions at the apices , as in [V3Cl3(mu(3)-Cl)(2)(tmeda)(3)](+), [V3Cl3(mu(3)-OMe)(2)(tmeda) (3)](+) and[V3Cl3(mu(3)-OMe)(2)(depe)(3)](+)