EXPERIMENTAL-OBSERVATION OF STABLE CYANODIAZONIUM IONS, NC-N-2(+)

Authors
CACACE F GRANDINETTI F PEPI F
Citation
F. Cacace et al., EXPERIMENTAL-OBSERVATION OF STABLE CYANODIAZONIUM IONS, NC-N-2(+), Journal of the Chemical Society, Chemical Communications, (18), 1994, pp. 2173-2174
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1994
Pages
2173 - 2174
Database
ISI
SICI code
0022-4936(1994):18<2173:EOSCIN>2.0.ZU;2-A
Abstract
The elusive cyanodiazonium ion, NC-N-2(+), proposed as a transient int ermediate in solution, but never directly observed, can be obtained in the gas phase by ionization of a mixture of nitrogen trifluoride and cyanamide, and characterized by collisionally activated dissociation ( CAD) mass spectrometry.