ON THE CONTROL OF THE SITE OF METHYLATION OF THE CYANIDE COMPLEX [MO-2(ETA(5)-C5H5)(2)(CO)(CN)(MU-SR)(2)]- BY THE SUBSTITUENTS OF THE THIOLATE BRIDGES (R=ME, PR-I, CF3)

Authors
ABASQ ML PETILLON FY TALARMIN J
Citation
Ml. Abasq et al., ON THE CONTROL OF THE SITE OF METHYLATION OF THE CYANIDE COMPLEX [MO-2(ETA(5)-C5H5)(2)(CO)(CN)(MU-SR)(2)]- BY THE SUBSTITUENTS OF THE THIOLATE BRIDGES (R=ME, PR-I, CF3), Journal of the Chemical Society, Chemical Communications, (18), 1994, pp. 2191-2192
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1994
Pages
2191 - 2192
Database
ISI
SICI code
0022-4936(1994):18<2191:OTCOTS>2.0.ZU;2-9
Abstract
The substituents of the bridging sulfur atoms exert an electronic cont rol on the site of methylation of the cyanide complex [Mo-2(eta(5)-C5H 5)(2)(CO)(CN)(mu-SR)2](-): the methylation can be diverted from a sulf ur lone pair to the cyanide ligand on changing the electronic properti es of the R groups from electron-releasing to electron-withdrawing, re spectively.