THE IONIZATION-ENERGY OF 2,8-DICHLORODIBENZO-P-DIOXIN BY RESONANCE-ENHANCED 2-PHOTON IONIZATION

Authors
GREBNER TL NEUSSER HJ ERNSTBERGER B
Citation
Tl. Grebner et al., THE IONIZATION-ENERGY OF 2,8-DICHLORODIBENZO-P-DIOXIN BY RESONANCE-ENHANCED 2-PHOTON IONIZATION, International journal of mass spectrometry and ion processes, 136(1), 1994, pp. 101-106
Citations number
13
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
International journal of mass spectrometry and ion processes → ACNP
ISSN journal
01681176
Volume
136
Issue
1
Year of publication
1994
Pages
101 - 106
Database
ISI
SICI code
0168-1176(1994)136:1<101:TIO2BR>2.0.ZU;2-3
Abstract
The adiabatic ionization energy (IE) of 2,8-dichlorodibenzo-p-dioxin i s measured using the method of resonance-enhanced multiphoton ionizati on (REMPI) combined with time-of-flight mass spectrometry (TOFMS), yie lding a value of 7.802(4) eV. This value is compared with previous the oretical results from the literature. Possible consequences for the de tection of higher chlorinated dibenzo-p-dioxins with the method of one -color two-photon ionization are discussed.