CHEMOSELECTIVE REDUCTION OF 2,3-EPOXY TOSYLATES WITH DIBAL-H AS A GENERAL-ROUTE TO ENANTIOMERICALLY-ENRICHED 1-TOSYLOXY-2-ALKANOLS

Authors
CHONG JM JOHANNSEN J
Citation
Jm. Chong et J. Johannsen, CHEMOSELECTIVE REDUCTION OF 2,3-EPOXY TOSYLATES WITH DIBAL-H AS A GENERAL-ROUTE TO ENANTIOMERICALLY-ENRICHED 1-TOSYLOXY-2-ALKANOLS, Tetrahedron letters, 35(39), 1994, pp. 7197-7200
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
39
Year of publication
1994
Pages
7197 - 7200
Database
ISI
SICI code
0040-4039(1994)35:39<7197:CRO2TW>2.0.ZU;2-2
Abstract
2,3-Epoxy tosylates may be reduced with DIBAL-H in CH2Cl2 or ether at -40 degrees Cto 1-tosyloxy-2-alkanols in high (94-98%) yields.