FRAGMENTATION-CYCLIZATION REACTIONS BY PHOTOINDUCED ELECTRON-TRANSFER

Authors
KIRSCHBERG T MATTAY J
Citation
T. Kirschberg et J. Mattay, FRAGMENTATION-CYCLIZATION REACTIONS BY PHOTOINDUCED ELECTRON-TRANSFER, Tetrahedron letters, 35(39), 1994, pp. 7217-7220
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
39
Year of publication
1994
Pages
7217 - 7220
Database
ISI
SICI code
0040-4039(1994)35:39<7217:FRBPE>2.0.ZU;2-R
Abstract
Irradiation of unsaturated bicyclo[4.1.0]heptanones and bicyclo[3.1.0] hexanones under reductive PET conditions leads to a regioselective cle avage of the cyclopropane moiety followed by cyclization. By this meth od various types of ring anellated and spirocyclic compounds are acces sible.