Metallic multilayered thin films have recently been investigated due t
o their new magnetic and transport properties. The interest here is fo
cussed on the characterization of the interfaces between the layers. T
he analysis of growth and structure of polycrystalline Cr/Au multilaye
rs is accomplished by two complementary techniques: in situ ultrahigh
vacuum scanning tunnelling microscopy and ex situ transmission electro
n microscopy. The combination of these powerful methods provides detai
led information about structural characteristics such as crystallite s
ize, surface roughness and crystallographic orientation. Moreover, con
clusions can be drawn on the atomic arrangement and growth mechanism a
t the Cr-Au interface. The results are supported by semiempirical and
theoretical expectations.