EXCITED-STATE FORMATION IN PULSE IRRADIATED POLYETHYLENE DOPED WITH AROMATICS

Citation
M. Szadkowskanicze et al., EXCITED-STATE FORMATION IN PULSE IRRADIATED POLYETHYLENE DOPED WITH AROMATICS, Radiation physics and chemistry, 45(1), 1995, pp. 87-91
Citations number
13
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
0969806X
Volume
45
Issue
1
Year of publication
1995
Pages
87 - 91
Database
ISI
SICI code
0969-806X(1995)45:1<87:EFIPIP>2.0.ZU;2-G
Abstract
The absorption/emission spectra and kinetics of excited states (single ts and triplets) and ions generated by pulse radiolysis method in the polyethylene-solute (dimethyldiphenyl, pyrene) systems were investigat ed. It was found that excited states of aromatic admixtures were forme d as a result of ion recombination in micro/millisecond time scales at temperatures higher than T-g. Solute excimer emission was observed fr om pulse-irradiated PE samples at room temperature. The mechanism of e xcimer formation was discussed.