Ln. Andreeva et al., ELASTIC DEFORMATIONS IN MAGNETIC-FIELD OF A LIQUID-CRYSTALLINE POLYMER HAVING MESOGEN GROUPS IN THE BACKBONE AND GRAFTED CHAINS, Vysokomolekularnye soedinenia. Seria A, 36(7), 1994, pp. 1137-1142
The elastic orientational deformations in magnetic field and the tempe
ratures of phase transitions were studied for a hybrid thermotropic li
quid-crystalline aromatic polyester, having mesogen groups in both bac
kbone and grafted chains in the range of molecular masses from 900 to
10200. It was found that in the studied range of molecular masses bire
fringence of totally oriented nematic and, hence, its orientational or
dering are independent of molecular mass. On changing the relative tem
perature from -2 to -30-degrees-C, the order parameter of orientation
increases from 0.35 to 0.55. The bend elastic constants are on the sam
e order with those of previously investigated nematics (both high- and
low-molecular-mass). No dependence of the constants upon molecular ma
ss was found.