WITTIG REACTION ON SOME ALDEHYDES FROM ALEURITIC ACID-DERIVATIVES ANDA SYNTHESIS OF (Z)-9-TRICOSENE

Authors
BHUSHAN KH RASTOGI A SUBRAMANIAN GBV
Citation
Kh. Bhushan et al., WITTIG REACTION ON SOME ALDEHYDES FROM ALEURITIC ACID-DERIVATIVES ANDA SYNTHESIS OF (Z)-9-TRICOSENE, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 33(10), 1994, pp. 966-970
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
33
Issue
10
Year of publication
1994
Pages
966 - 970
Database
ISI
SICI code
0376-4699(1994)33:10<966:WROSAF>2.0.ZU;2-H
Abstract
Starting from the commercially available threo-aleuritic acid (1a) and its erythro-isomer (5), Wittig reactions have been carried out using several procedures on the aldehydes available by CrO3-Py oxidation of the terminal hydroxyl function. From the 16-iodo derivative (6) of ery thro-aleuritic acid, through Wittig reaction followed by reductions an d olefination of the 1,2-glycol function, (Z)-9-tricosene (4) has been synthesised.