Air stripping is an effective and economical process for removing vola
tile organic chemicals (VOCs) from contaminated water sources. However
the air stripping process simply transfers the contaminants from the
water to the air phase where they may continue to pose an environmenta
l problem. In this study, the use of ultraviolet light (u.v.) photooxi
dation for treating the off gas from air stripping is examined. Subseq
uent papers will address linking u.v. photooxidation with air strippin
g in a closed loop stripping process. Fundamental studies are conducte
d to characterize the kinetics of the gas phase photooxidation of five
volatile chlorinated alkanes and alkenes under different operating co
nditions.