ISOLATION AND CHARACTERIZATION OF MONOMERIC MONO(IODOSYLBENZENE) MANGANESE(IV) TETRAPHENYLPORPHYRIN COMPLEXES FROM THE (TETRAPHENYLPORPHINATO) MANGANESE(III) DERIVATIVES IODOSYLBENZENE SYSTEMS AND THEIR OXIDATION PROPERTIES

Authors
JIN RZ CHO CS JIANG LH SHIM SC
Citation
Rz. Jin et al., ISOLATION AND CHARACTERIZATION OF MONOMERIC MONO(IODOSYLBENZENE) MANGANESE(IV) TETRAPHENYLPORPHYRIN COMPLEXES FROM THE (TETRAPHENYLPORPHINATO) MANGANESE(III) DERIVATIVES IODOSYLBENZENE SYSTEMS AND THEIR OXIDATION PROPERTIES, Journal of molecular catalysis. A, Chemical, 116(3), 1997, pp. 343-347
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
116
Issue
3
Year of publication
1997
Pages
343 - 347
Database
ISI
SICI code
1381-1169(1997)116:3<343:IACOMM>2.0.ZU;2-Z
Abstract
The monomeric mono(iodosylbenzene) (tetraphenylporphinato)manganese(IV ) derivatives, LMn(IV)TPP(OIPh) (2a and 2b) (L = 4-MeOC(6)H(4)O(-) and 4-t-BuC(6)H(4)O(-)) have been synthesized from the reaction of the co rresponding (tetraphenylporphinato)manganese(III) derivatives 1a and 1 b, LMn(III)TPP with iodosylbenzene, respectively. The complexes 2a and 2b have been characterized by elemental analyses, visible, infrared a nd ESR spectroscopy. These complexes are capable of oxidizing cyclohex ane and styrene to give oxidation products in high yields at room temp erature.