Citation
Ac. Benyei et al., TRANSFER HYDRODEHALOGENATION OF ORGANIC HALIDES CATALYZED BY WATER-SOLUBLE RUTHENIUM(II) PHOSPHINE COMPLEXES, Journal of molecular catalysis. A, Chemical, 116(3), 1997, pp. 349-354
Citations number
45
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
13811169
Volume
116
Issue
3
Year of publication
1997
Pages
349 - 354
Database
ISI
SICI code
1381-1169(1997)116:3<349:THOOHC>2.0.ZU;2-K
Abstract
C-X bonds in carbon tetrachloride, chloroform and 1-hexyl halogenides
were transformed into C-H bonds in a transfer hydrodehalogenation reac
tion catalyzed by water soluble ruthenium(II) phosphine complexes. A t
urnover frequency of up to 1000 h(-1) can be achieved when an aqueous
solution of sodium formate is the hydrogen donor and RuCl2(TPPMS)(2) (
1) the catalyst (TPPMS = m-sulfophenyl diphenylphosphine sodium salt).