HIGHLY STEREOSELECTIVE SUBSTITUTION-REACTIONS OF FUNCTIONALIZED ETA(4)-[3(E),5(E)-HEPTADIEN-2-OL]IRON TRICARBONYL COMPLEXES

Authors
ROUSH WR WADA CK
Citation
Wr. Roush et Ck. Wada, HIGHLY STEREOSELECTIVE SUBSTITUTION-REACTIONS OF FUNCTIONALIZED ETA(4)-[3(E),5(E)-HEPTADIEN-2-OL]IRON TRICARBONYL COMPLEXES, Tetrahedron letters, 35(40), 1994, pp. 7347-7350
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
40
Year of publication
1994
Pages
7347 - 7350
Database
ISI
SICI code
0040-4039(1994)35:40<7347:HSSOFE>2.0.ZU;2-V
Abstract
Substituted eta(4)-[3(E),5(E)-heptadien-2-ol)Fe(CO)(3) complexes 10a,b , 11a,b or the corresponding acetate derivatives 14, 20, 23, 25 and 28 undergo highly stereoselective Lewis acid mediated substitution react ions with various nucleophiles, including R(3)Al reagents, ketene sily l acetals, allyltributylstannane, allyltrimethylsilane, and trimethyls ilylazide. Evidence is presented that these reactions proceed with ret ention of configuration.