TRIALKYLAMMONIUM-TRIALKYLAMINE-TETRAPHENYLBORATES [R(3)N(CIRCLE-PLUS)-H TER-DOT-CENTER-DOT-NR(3)][B-CIRCLE-MINUS(C6H5)(4)] WITH PROTOTYPE N-CIRCLE-PLUS-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-N HYDROGEN BRIDGES

Authors
BOCK H VAUPEL T SCHODEL H KOCH U EGERT E
Citation
H. Bock et al., TRIALKYLAMMONIUM-TRIALKYLAMINE-TETRAPHENYLBORATES [R(3)N(CIRCLE-PLUS)-H TER-DOT-CENTER-DOT-NR(3)][B-CIRCLE-MINUS(C6H5)(4)] WITH PROTOTYPE N-CIRCLE-PLUS-H-CENTER-DOT-CENTER-DOT-CENTER-DOT-N HYDROGEN BRIDGES, Tetrahedron letters, 35(40), 1994, pp. 7355-7358
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
40
Year of publication
1994
Pages
7355 - 7358
Database
ISI
SICI code
0040-4039(1994)35:40<7355:T[>2.0.ZU;2-0
Abstract
Protonation of trialkylamines in the presence of the non-protonable an ion tetraphenylborate allows to crystallize [R(3)N(+)-H... NR(3)] salt s with trimethylamine, quinuclidine, diazabicyclooctane or pyridine. T heir single crystal structures are rationalized by SCF and force-field calculations.