METATHESIS OF OMEGA-UNSATURATED GLUCOSIDES WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN, AS A NEW WAY LEADING TO UNSATURATED BOLAAMPHIPHILES

Citation
G. Descotes et al., METATHESIS OF OMEGA-UNSATURATED GLUCOSIDES WITH CHLORO-ARYLOXIDE COMPLEXES OF TUNGSTEN, AS A NEW WAY LEADING TO UNSATURATED BOLAAMPHIPHILES, Tetrahedron letters, 35(40), 1994, pp. 7379-7382
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
40
Year of publication
1994
Pages
7379 - 7382
Database
ISI
SICI code
0040-4039(1994)35:40<7379:MOOGWC>2.0.ZU;2-7
Abstract
Glucosides of unsaturated alcohols, bearing different protecting soups at glucose units underwent catalytic metathesis affording bolaamphiph iles with good yields. Tungsten aryloxo-complexes (1 and 2) were found to be superior catalysts for this process.