Aa. Russell et al., FREQUENCY AND ATTENUATION RESPONSE OF ACOUSTIC PLATE MODE DEVICES COATED WITH POROUS OXIDE-FILMS, Analytical chemistry, 66(19), 1994, pp. 3108-3116
The response behavior of coated acoustic plate mode (APM) devices upon
exposure to ionic solutions was evaluated. The response sensitivity (
frequency shifts and attenuation) of APM devices coated with porous ox
ide films increased by factors of ca. 4-30 compared with an uncoated d
evice upon exposure to ionic solutions. These responses arise predomin
antly due to acoustoelectric coupling and are consistent with enhanced
pore conductivity. A previously derived model for the acoustoelectric
response of uncoated APMs is inadequate for predicting the magnitude
of coated APM responses and needs to be modified to account for the pr
operties of porous films. Frequency responses are consistent with enha
nced conductivity of the solution within the porous coatings. Film por
osity, pore size distribution, and film thickness are identified as pa
rameters influencing response sensitivity.