Membranes have been fabricated from organic-based TiO2 sols via a coat
ing process. This process produces an essentially flaw-free membrane.
Gas permeability experiments employing these membranes indicate that t
hese membranes possess unique properties. These membranes exhibit rela
tively high permeabilities to propylene at low pressures. This propert
y of these membranes can be attributed to a mechanism involving some f
orm of condensed phase transport. The data also indicate that transpor
t of helium, oxygen and nitrogen involves, to some extent, a form of s
urface transport.