The icosahedral metastable Al-Mn phase was obtained in thin films prep
ared by the high temperature sequential vapor deposition method. Analy
sis of X-ray diffraction line profiles allows an estimate of the rando
m phason strain, revealing the presence of a highly disordered icosahe
dral fraction. Its concentration is correlated with the degree of crys
tallographic perfection of the Al substrate. Thereby, the crucial role
of Al diffusion in the formation of the icosahedral phase is evidence
d.