SIMULTANEOUS FORMATION OF TITANIUM NITRIDE AND TITANIUM SILICIDE IN AONE-STEP PROCESS IN HETEROGENEOUS PHASE DURING MULTIPULSE LASER TREATMENT OF A SI WAFER WITH A THIN TI COATING IN SUPERATMOSPHERIC N2
In. Mihailescu et al., SIMULTANEOUS FORMATION OF TITANIUM NITRIDE AND TITANIUM SILICIDE IN AONE-STEP PROCESS IN HETEROGENEOUS PHASE DURING MULTIPULSE LASER TREATMENT OF A SI WAFER WITH A THIN TI COATING IN SUPERATMOSPHERIC N2, Thin solid films, 251(1), 1994, pp. 23-29
We have succeeded in simultaneously conducting two chemical reactions
resulting in the formation of titanium nitride and titanium silicide i
n well-shaped clearly separated layers as an effect of multipulse exci
mer laser treatment of a Si wafer with a thin Ti coating in an ambient
N2 gas. We demonstrate by a numerical analysis that the parallel evol
ution of the two reactions in a one-step process is a consequence of t
he melting of both the Ti coating and of a thick layer of Si bulk in c
onditions that completely avoided substance expulsion.