ORGANOMETAL LEWIS-ACIDS .53. COORDINATION OF ORGANOMETAL LEWIS-ACIDS WITH TRANSITION METAL-BONDED NITRILE AND CARBONYL GROUPS

Authors
WIESER M MISSLING C ROBL C BECK W
Citation
M. Wieser et al., ORGANOMETAL LEWIS-ACIDS .53. COORDINATION OF ORGANOMETAL LEWIS-ACIDS WITH TRANSITION METAL-BONDED NITRILE AND CARBONYL GROUPS, Journal of organometallic chemistry, 479(1-2), 1994, pp. 227-235
Citations number
51
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
479
Issue
1-2
Year of publication
1994
Pages
227 - 235
Database
ISI
SICI code
0022-328X(1994)479:1-2<227:OL.COO>2.0.ZU;2-3
Abstract
The addition of (OC)5Re+, Cp(OC)(Ph3P)M+ (M = Fe, Ru), Cp(Ph3P)2Ru+, ( OC)5M (M = Cr, W) and Cp(OC)2Mn to the nitrile groups of Cp(OC)2FeCH2C N, Cp(OC)2FeCH2CH2CN and (OC)3Fe(eta4-C6H7CN), and of (OC)5Re' to the carbonyl group Cp(OC)2FeCH2CHO, yields the organonitrile-bridged compl exes [Cp(OC)2FeCH2CNRe(CO)5]BF4, [CP(OC)2FeCH2CH2CNRe (CO)5]BF4, [(OC) 3Fe(eta4-C6H7CNRe(CO)5)]BF4. [CP(OC)2FeCH2CNM(CO)(PPh3)Cp]BF4, [CP(OC) 2FeCH2CH2CNM(CO) (PPh3)Cp]BF4 (M = Fe, Ru), [CpFe(eta5-C5H4CH2CNRu(PPh 3)2Cp)]BF4, CP(OC)2FeCH2CNM(CO)5, CP(OC)2FeCH2CH2CNM (CO)5, (OC)3Fe(et a4-C6H7CNM(CO)5) (M = Cr, W), Cp(OC)2FeCH2CNMn(CO)2Cp and [CP(OC)2FeCH 2CHORe(CO)5]BF4, respectively. The structure of [CP(OC)2FeCH2CNRe(CO)5 ]BF4 has been determined by X-ray diffraction.