CHLOROPOLYFLUORODIETHYL ETHERS

Authors
COE PL LENNARD MS TATLOW JC
Citation
Pl. Coe et al., CHLOROPOLYFLUORODIETHYL ETHERS, Journal of fluorine chemistry, 80(2), 1996, pp. 87-90
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
80
Issue
2
Year of publication
1996
Pages
87 - 90
Database
ISI
SICI code
0022-1139(1996)80:2<87:CE>2.0.ZU;2-P
Abstract
Fluorination of 2-chlorodiethyl ether by cobalt trifluoride at 110-150 degrees C afforded isomers of 2-chloro-pentafluoro-, -hexafluoro-, an d -heptafluoro- diethyl ethers. Chlorine was lost in similar fluorinat ions of 2-chloro-2,2-difluoroethyl ethyl ether, the only products isol ated being a hepta- and a hexa-fluoro diethyl ether. Structures were e stablished spectroscopically.