THE CRYSTAL-STRUCTURE OF [BIS(TRI-(T)BUTYL-PHOSPHINE)GOLD(I)] CHLORIDE

Authors
ZELLER E SCHIER A SCHMIDBAUR H
Citation
E. Zeller et al., THE CRYSTAL-STRUCTURE OF [BIS(TRI-(T)BUTYL-PHOSPHINE)GOLD(I)] CHLORIDE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(9), 1994, pp. 1243-1246
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
9
Year of publication
1994
Pages
1243 - 1246
Database
ISI
SICI code
0932-0776(1994)49:9<1243:TCO[C>2.0.ZU;2-K
Abstract
The title compound is available from the reaction of labile gold(I) ch loride complexes and an excess of the ligand ((t)Bu(3)P), or from the NaBH4 reduction of ((t)Bu(3)P)AuCl. It forms dark red cubic crystals, [a = 14.297(1) Angstrom at -56 degrees C, space group P2(1)3, Z = 4]: with isolated chloride anions and [((t)Bu(3)P)(2)Au](+) cations of C-3 symmetry, with linear two-coordinate gold centers.