DOUBLE MICHAEL REACTION OF CARVONE AND IT S UTILIZATION IN CHIRAL SYNTHESIS OF NATURAL-PRODUCTS

Authors
ZHAO YF ZHAO RB WU YL
Citation
Yf. Zhao et al., DOUBLE MICHAEL REACTION OF CARVONE AND IT S UTILIZATION IN CHIRAL SYNTHESIS OF NATURAL-PRODUCTS, Huaxue xuebao, 52(8), 1994, pp. 823-830
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
52
Issue
8
Year of publication
1994
Pages
823 - 830
Database
ISI
SICI code
0567-7351(1994)52:8<823:DMROCA>2.0.ZU;2-5
Abstract
The double Michael reaction of carvene and methyl methacrylate was des cribed in detail. Its product, an optically active bicyclo [2.2.2]octa ne derivative, is a useful intermediate for the chiral synthesis of na tural products. In this respect an elemene derivative and an intermedi ate for the synthesis of (+)-curdione were synthesized.