Me. Kuehne et al., SYNTHESES OF STRYCHNOS-TYPE AND ASPIDOSPERMATAN-TYPE ALKALOIDS .5. TOTAL SYNTHESES OF (+ -)-ECHITAMIDINE AND 20-EPI- AND 19-EPI-20-EPI-ECHITAMIDINE/, Journal of organic chemistry, 59(20), 1994, pp. 5977-5982
Intramolecular Diels-Alder reactions, at two stages in the reaction se
quence, provided total syntheses of the racemate of the hypotensive al
kaloid echitamidine (8) and of its C-19,20 and C-20 epimers 9a and 9b.