M. Ishida et al., CORROSION OF MULTILAYERS USED FOR MAGNETO RESISTIVE HEAD IN AQUEOUS-SOLUTION ENVIRONMENT, Nippon Kinzoku Gakkaishi, 61(1), 1997, pp. 64-70
Magnetoresistive heads (MR heads), which utilize the magnetoresistive
effect of ferromagnetic films, are consisted of metal multilayer films
. The metal multilayers of the MR heads should cause galvanic corrosio
n in the water environment. The aim of this study is to make clear the
corrosion behavior of the metal multilayers used for MR heads. To inv
estigate the corrosion of real MR heads, the corrosion test of simulat
ed MR head samples having the structure of Au/Fe-Mn/Ni-Fe/Ta/Ni-Fe-Cr
was performed in 0.1 kmol . m(-3)NaCl and 0.1 kmol . m(-3)Na(2)SO(4).
Corrosion and electrochemical behavior of each metal film was examined
in pH 8.45 boric-borate buffer, 0.1 kmol . m(-3)NaCl and 0.1 kmol . m
(-3)Na(2)SO(4). Galvanic current measurement was performed in the same
solutions on galvanic couples of Au and Fe-Mn films or Fe-Mn and Ni-F
e films. It has been found that Fe-Mn films do not suffer from corrosi
on in pH 8.45 boric-borate buffer owing to the formation of passive fi
lms. In 0.1 kmol . m(-3)NaCl and 0.1 kmol . m(-3)Na(2)SO(4), however,
the films suffer from serious pitting corrosion. Moreover, couples of
Au and Fe-Mn films or those of Ni Fe and Fe-Mn films cause galvanic co
rrosion in the same solutions and the corrosion rate increases with in
creasing area ratio of Au or the Ni-Fe film to the Fe-Mn film.