NEW WATER-SOLUBLE RHODIUM-CONTAINING CATALYSTS FOR THE HYDROFORMYLATION OF 1-HEXENE

Authors
KOLESNICHENKO NV MURZABEKOVA TK MARKOVA NA SHARIKOVA MV DEMINA YM SLIVINSKII YV VASILYEVA YA TOPCHIYEV DA
Citation
Nv. Kolesnichenko et al., NEW WATER-SOLUBLE RHODIUM-CONTAINING CATALYSTS FOR THE HYDROFORMYLATION OF 1-HEXENE, Petroleum chemistry, 34(3), 1994, pp. 213-217
Citations number
8
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
34
Issue
3
Year of publication
1994
Pages
213 - 217
Database
ISI
SICI code
0965-5441(1994)34:3<213:NWRCFT>2.0.ZU;2-Z
Abstract
An investigation has been made of the influence of the nature of the c ounterion and radical at the nitrogen atom in polycations on the catal ytic properties of rhodium complexes based on them. It has been shown that a catalytic system based on a dihydrophosphate polycation contain ing a hydrogen radical and a counterion (a dihydrophosphate anion) at the nitrogen atom exhibits not only fairly high activity, but also hig h stability.