Dyakov (1954) and Kontorovich (1957) formulated the conditions for cor
rugation instability of shock waves as well as for spontaneous emissio
n of sound and entropy-vortex waves from them. For the first time sinc
e then, it is shown here that physical circumstances do exist under wh
ich shocks in gases spontaneously emit sound waves. Such circumstances
are provided by strong ionizing shocks. In order to see that, the coe
fficient of reflection of an acoustic wave from a shock is derived as
a function of the wave's frequency and the ionization degree. Spontane
ous emission of sound occurs when the reflection coefficient becomes i
nfinitely large. It is shown that the relevant frequency range for the
occurrence of spontaneous emission is that for which the electrons ar
e not in local thermodynamic equilibrium with the heavy particles. The
special properties of acoustic perturbations behind the ionizing shoc
k are considered for this frequency range and the sound velocity in a
partially ionized gas is derived. In addition, the condition for spont
aneous emission of sound is modified in order to take into account the
difference between the electrons and heavy-particle perturbed tempera
tures. It is shown, by numerical calculations, that the criterion for
spontaneous emission is satisfied behind ionizing shocks in argon. In
particular, for an initial pressure of 5 Torr, the threshold for the o
ccurrence of the spontaneous emission is found to be M(1) = 15. This c
ritical value of the shock Mach number, as well as other calculated ph
ysical features, agree very well with those obtained experimentally by
Glass and Liu (1978) who observed the occurrence of instability behin
d shocks in argon.