SYNTHESIS AND REACTIVITY OF FURAZANYLDIAZONIUM AND FUROXANYLDIAZONIUMSALTS

Authors
RAKITIN OA ZALESOVA OA KULIKOV AS MAKHOVA NN GODOVIKOVA TI KHMELNITSKII LI
Citation
Oa. Rakitin et al., SYNTHESIS AND REACTIVITY OF FURAZANYLDIAZONIUM AND FUROXANYLDIAZONIUMSALTS, Russian chemical bulletin, 42(11), 1993, pp. 1865-1870
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
11
Year of publication
1993
Pages
1865 - 1870
Database
ISI
SICI code
1066-5285(1993)42:11<1865:SAROFA>2.0.ZU;2-P
Abstract
Diazotization of aminofurazans (1) and 4-aminofuroxans (2) with nitros ylsulfuric acid in a mixture of conc. H2SO4 and H3PO4 has been studied and offered as a general method for preparing furazanyl- (3) and furo xanyldiazonium (4) salts. It has been shown that reactions with the re tention of the N-N-group (azo coupling, formation of triazenes and azi des) are typical of salts 3 and 4, while elimination of the N2 molecul e (Sandmeyer reaction, hydrolysis, reduction) is not typical.