PARTICIPATION OF HYDROGEN-BONDS IN THE PROTONATION OF (ETA(5)-C5ME5)M(CO)2, M=IR, RH

Authors
SHUBINA ES KRYLOV AN MURATOV DV FILCHIKOV AA EPSTEIN LM
Citation
Es. Shubina et al., PARTICIPATION OF HYDROGEN-BONDS IN THE PROTONATION OF (ETA(5)-C5ME5)M(CO)2, M=IR, RH, Russian chemical bulletin, 42(11), 1993, pp. 1919-1920
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
11
Year of publication
1993
Pages
1919 - 1920
Database
ISI
SICI code
1066-5285(1993)42:11<1919:POHITP>2.0.ZU;2-2
Abstract
The interaction of CpM(CO)2 (M = Ir or Rh) with CF3COOH in low polar media results in partial protonation of these compounds giving molecul ar (M...HO) and ionic (MH+...O-) hydrogen-bonded complexes. According to IR spectral data, a decrease in temperature results in a shift of t he equilibrium toward the ionic forms. These compounds react with phen ol to give molecular complexes only.