HIGH-FREQUENCY STRUCTURAL RELAXATION IN SODIUM SILICATES - A MOLECULAR DYNAMIC STUDY

The dynamic behavior of sodium silicate liquid and glassy structures w ere investigated by means of molecular dynamic simulations. Particle i nteractions were modeled using the central force Born-Mayer potential. Simulations were carried out over approximately half a nanosecond. Dy namic susceptibility spectra describing the response of the alkali cat ions to thermal activation are reported for various temperatures. The diffusion of alkali cations was found to be solid-like, i.e., occurrin g as sudden jumps separated by long waiting periods, even above the gl ass transition temperature. The intermediate scattering functions appr oximately follow a stretched exponential behaviour, with a stretching exponent of 0.8. The characteristic relaxation times for cation motion depend on the probing wave vector according to a power law, with an e xponent close to -2.