USE OF A CHROMIUM TRICARBONYL COMPLEX IN A DIELS-ALDER REACTION - IMPROVED PREPARATION OF ANGULARLY TRIFLUOROMETHYL-SUBSTITUTED TETRAHYDROPHENANTHRONE

Authors
BONNETDELPON D LEQUEUX T GRUSELLE M MALEZIEUX B
Citation
D. Bonnetdelpon et al., USE OF A CHROMIUM TRICARBONYL COMPLEX IN A DIELS-ALDER REACTION - IMPROVED PREPARATION OF ANGULARLY TRIFLUOROMETHYL-SUBSTITUTED TETRAHYDROPHENANTHRONE, Applied organometallic chemistry, 8(6), 1994, pp. 551-552
Citations number
12
Categorie Soggetti
Chemistry Applied","Chemistry Inorganic & Nuclear
Journal title
Applied organometallic chemistry → ACNP
ISSN journal
02682605
Volume
8
Issue
6
Year of publication
1994
Pages
551 - 552
Database
ISI
SICI code
0268-2605(1994)8:6<551:UOACTC>2.0.ZU;2-9
Abstract
The tricarbonyl complex prepared from 1-trifluoromethyldihydronaphthal ene and Cr(CO)3(NH3)3 undergoes Diels-Alder cycloaddition under high-p ressure conditions (15 kbar) to give after decomplexation by natural l ight and deprotection, the tetrahydrophenanthrone product in 65% yield . This new methodology allows the activation of unreactive styrenes in Diels-Alder cycloaddition.