We report on XPS results that show an inhomogeneous charge effect, gre
ater than 1.0 eV and far greater than the accuracy of the measurements
(approximately 0.2 eV), exhibited by a natural mineral essentially co
mposed of SiO2 and Fe2O3. This mineral has proved to be an efficient c
atalyst in a Fischer-Tropsch reaction. We have corrected this differen
tial charge effect by using two internal references in order to interp
ret satisfactorily our XPS data.