DENSITIES, VISCOSITIES, AND EXCESS PROPERTIES OF TRIFLUOROETHANOL-WATER, TETRAETHYLENE GLYCOL DIMETHYLETHER-WATER, AND TRIFLUOROETHANOL-TETRAETHYLENE GLYCOL DIMETHYLETHER AT 303.15-K
F. Olive et al., DENSITIES, VISCOSITIES, AND EXCESS PROPERTIES OF TRIFLUOROETHANOL-WATER, TETRAETHYLENE GLYCOL DIMETHYLETHER-WATER, AND TRIFLUOROETHANOL-TETRAETHYLENE GLYCOL DIMETHYLETHER AT 303.15-K, International journal of thermophysics, 15(4), 1994, pp. 661-674
Densities and kinematic viscosities of trifluoroethanol + water, tetra
ethylene glycol dimethylether + water, and trifluoroethanol + tetraeth
ylene glycol dimethylether have been measured at 303.15 K and atmosphe
ric pressure over the entire range of composition. Dynamic viscosities
, excess volumes, excess viscosities, and excess Gibbs energies of act
ivation of flow were obtained from the experimental results. The exces
s volumes were negative, whereas excess viscosities and energies of ac
tivation were positive, presenting the three thermodynamic properties
asymmetric composition dependence. The kinematic viscosities were used
to test McAllister, Stephan, and Soliman and Marshall correlations.