THERMAL-PROPERTIES OF AMINOPOLYCARBOXYLIC ACID-SOLUTIONS IN THE TEMPERATURE-RANGE 20-80-DEGREES-C

Citation
Mbs. Osman et Az. Dakroury, THERMAL-PROPERTIES OF AMINOPOLYCARBOXYLIC ACID-SOLUTIONS IN THE TEMPERATURE-RANGE 20-80-DEGREES-C, International journal of thermophysics, 15(4), 1994, pp. 675-686
Citations number
5
Categorie Soggetti
Physics, Applied","Chemistry Physical
ISSN journal
0195928X
Volume
15
Issue
4
Year of publication
1994
Pages
675 - 686
Database
ISI
SICI code
0195-928X(1994)15:4<675:TOAAIT>2.0.ZU;2-K
Abstract
The thermal properties (thermal conductivity, thermal diffusivity, and volumetric heat capacity) of aminopolycarboxylic acids, nitrilotriace tic acid (NTA), ethylenediaminetetraacetic acid (EDTA), diethylenetria minepentaacetic acid (DTPA), triethylenetetraminehexaacetic acid (TTHA ), 1,2-diaminocyclohexanetetraacetic acid (DCTA), and ethyleneglycol-b is-(2-aminoethylether) tetraacetic acid (EGTA), in dilute solutions of sodium hydroxide were measured in the temperature range 20-80-degrees -C. The measurements were performed with a hot-wire (strip) technique. The results show that the values of the thermal properties depend on the number of nitrogen atoms and the number of carboxyalkyl groups, wh ich are bounded to the nitrogen atom, of the aminopolycarboxylic acid and also on the concentration of the investigated compounds in the med ium and the temperatures. The mechanism of heat transfer is discussed and the role of convection is taken into consideration.