EXCESS THERMODYNAMIC PROPERTIES OF MIXTURES OF ALKYL BENZOATES WITH N-HEPTANE

Authors
BLANCO AM ORTEGA J
Citation
Am. Blanco et J. Ortega, EXCESS THERMODYNAMIC PROPERTIES OF MIXTURES OF ALKYL BENZOATES WITH N-HEPTANE, International journal of thermophysics, 15(4), 1994, pp. 699-710
Citations number
11
Categorie Soggetti
Physics, Applied","Chemistry Physical
Journal title
International journal of thermophysics → ACNP
ISSN journal
0195928X
Volume
15
Issue
4
Year of publication
1994
Pages
699 - 710
Database
ISI
SICI code
0195-928X(1994)15:4<699:ETPOMO>2.0.ZU;2-1
Abstract
The paper reports h(E) values at 298.15 K and upsilon(E) and deltaeta values at various temperatures for binary mixtures of propyl or butyl benzoate and n-heptane. The excess Gibbs energy of viscous flow, DELTA gE, and the thermodynamic activation properties were calculated from these values. The results are compared with those for similar mixtures and interpreted on the basis of the characteristic dipole-dipole inte ractions of alkyl esters.