Hw. Scholz et al., PURITY AND RADIOACTIVE DECAY BEHAVIOR OF INDUSTRIAL 2D-REINFORCED SICF SIC COMPOSITES/, Journal of nuclear materials, 215, 1994, pp. 655-661
Ceramic matrix composites based on SiC with continuous fibres (SiCf/ S
iC) are considered promising structural materials for future fusion de
vices. It was still to clarify, whether impurities in industrial SiCf/
SiC could jeopardise radiological advantages. Experimental impurity a
nalyses revealed a two-dimensionally reinforced SiCf/SiC with the matr
ix produced by CVI as very pure. Chemo-spectrometric methods were comb
ined with radioactivation methods (CPAA, NAA). A quantification of the
main constituents Si, C and O was added. Calculations with the FISPAC
T-2.4 code and EAF-2 library identified elements detrimental for diffe
rent low-activation criteria. For the neutron exposure, EEF reactor-st
udy first wall and blanket conditions were simulated. The calculated S
iCf/SiC included 48 trace elements. Even under conservative assumption
s, all low-activation limits of European interest are fulfilled. Exclu
sively the hands-on recycling limit for the First Wall can intrinsical
ly not be satisfied with SiC. The theoretical goal of a SiCf/SiC deple
ted of Si-28 (isotopic tailoring) is critically discussed.