A NEW-TYPE OF INTRAMOLECULAR H...H...H INTERACTION INVOLVING N-H...H(IR)...H-N ATOMS - CRYSTAL AND MOLECULAR-STRUCTURE OF (2)(ETA(2)-SC5H4N)(PCY3)]BF4-CENTER-DOT-0.72CH2CL2

Authors
PARK SH RAMACHANDRAN R LOUGH AJ MORRIS RH
Citation
Sh. Park et al., A NEW-TYPE OF INTRAMOLECULAR H...H...H INTERACTION INVOLVING N-H...H(IR)...H-N ATOMS - CRYSTAL AND MOLECULAR-STRUCTURE OF (2)(ETA(2)-SC5H4N)(PCY3)]BF4-CENTER-DOT-0.72CH2CL2, Journal of the Chemical Society, Chemical Communications, (19), 1994, pp. 2201-2202
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
19
Year of publication
1994
Pages
2201 - 2202
Database
ISI
SICI code
0022-4936(1994):19<2201:ANOIHI>2.0.ZU;2-1
Abstract
The iridium complexes, H(eta(1)-SC5H4NH)(2)(eta(2)-SC5H4N)(PCy(3))](BF 4), 1, and rH(eta(1)-SC5H4NH)(2)(eta(1)-SC5H4NH)(2)(PCy(3))]- (BF4)(2) , 2, [Cy = cyclohexyl] in the solid state and in CD2Cl2 solution conta in a new type of intramolecular H...H...H interaction contained in ten -membered bicyclic rings S-C-N-H...H(Ir)...H-N-C-S defined by the two 2-pyridiniumthiolate ligands coordinated in a monodentate fashion via sulfur to an iridium atom.