MODELS FOR BIMETALLIC CATALYSTS - SELECTIVITY IN LIGAND ADDITION AS AFUNCTION OF RHENIUM OXIDATION-STATE IN PT3RE CLUSTERS

Authors
XIAO JL HAO LJ PUDDEPHATT RJ MANOJLOVICMUIR L MUIR KW TORABI AA
Citation
Jl. Xiao et al., MODELS FOR BIMETALLIC CATALYSTS - SELECTIVITY IN LIGAND ADDITION AS AFUNCTION OF RHENIUM OXIDATION-STATE IN PT3RE CLUSTERS, Journal of the Chemical Society, Chemical Communications, (19), 1994, pp. 2221-2222
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
19
Year of publication
1994
Pages
2221 - 2222
Database
ISI
SICI code
0022-4936(1994):19<2221:MFBC-S>2.0.ZU;2-Q
Abstract
The ligands CO, P(OR)(3), and X- (X = Cl, Br, I) add selectively to th e Re and Pt-3 sites in the coordinatively unsaturated clusters [Pt-3{R e(CO)(3)}(mu-dppm)(3)](+) and [Pt-3{ReO3}(mu-dppm)(3)](+) respectively , dppm = Ph(2)PCH(2)PPh(2): the selectivity thus displays a remarkable dependency on the oxidation state of rhenium.