G. Sankar et al., PROBING ACTIVE-SITES IN SOLID CATALYSTS FOR THE LIQUID-PHASE EPOXIDATION OF ALKENES, Journal of the Chemical Society, Chemical Communications, (19), 1994, pp. 2279-2280
Using X-ray absorption fine structure measurements with a synchrotron
source, the local environment of the titanium-centred active site of a
siliceous mesoporous catalyst for the epoxidation of cyclohexene by H
2O2 has been determined prior to the onset and during the course of ca
talysis.